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Environment and Water Treatment-Treatment of Effluent

Oxidative pre-treatment of industrial effluents with hydrogen peroxide can reduce toxicity and chemical oxygen demand (COD) thereby improving the biodegradability of the waste water. OXYPER® S sodium carbonate peroxyhydrate is an effective solid carrier for hydrogen peroxide which is easy to store and handle and therefore ideal for use in case of emergencies.

Hydrogen peroxide reacts directly with many commonly occurring inorganic pollutants for example - chlorine, cyanide, formaldehyde, sulphide, sulphite and thiosulphate. In many cases the additional alkali present from the soda ash in OXYPER® S products helps with the rapid destruction of the pollutant. Such pollutants are oxidised to less noxious products thus reducing their contribution to the oxygen demand of the effluent and often resulting in control of noxious odours.

Hydrogen peroxide treatments are best applied at the pollutant source. Treating the pollutant when it is at its highest strength in the waste water reduces the consumption of hydrogen peroxide. 

TABLE : PEROXYGEN TREATMENTS AND PRODUCTS OF TREATMENT FOR COMMONLY OCCURRING WASTE WATER POLLUTANTS

POLLUTANT/CONDITIONS

PEROXYGEN TREATMENT

PRODUCTS

Oxygenation

H2O2

Dissolved Oxygen

Chlorine

Alkaline H2O2

Chloride

Cyanide

Alkaline H2O2

Cyanate (which hydrolyses to ammonia and carbonate)

Formaldehyde

Alkaline H2O2

Formate and CO2

Odour

Pollutant dependent - acidic or alkaline H2O2

Pollutant dependent

Sulphide

Acidic of alkaline H2O2

Sulphate and sulphur (pH dependent)

Sulphite

Acidic or alkaline H2O2

Sulphate

Thiosulphate

Acidic or alkaline H2O2

Sulphate and tetrathionate (pH dependent)



In most alkaline treatments OXYPER® S (sodium carbonate peroxyhydrate) can be used as an alternative to hydrogen peroxide.





Typical products

Percarbonate

Sodium Carbonate Peroxyhydrate



 
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